Synthesis, structural and theoretical studies of an iron-gallium(I) heterocycle complex:: Analogies with N-heterocyclic carbene chemistry

被引：44

作者：

Baker, RJ ^{[1
]}

Jones, C ^{[1
]}

Platts, JA ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

DALTON TRANSACTIONS | 2003年 / 19期

关键词：

D O I：

10.1039/b308616j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first iron complex of an anionic gallium N-heterocyclic carbene analogue, [Fe(CO)(4){Ga[N(Ar)C(H)](2)}](-) Ar = C6H3Pr2i -2,6, has been prepared and shown to have an unusual polymeric structure in the solid state; theoretical studies have pointed toward minimal Fe --> Ga back-bonding in this complex.

引用

页码：3673 / 3674

页数：2

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