Oxygen evolving reactions catalysed by synthetic manganese complexes: A systematic screening

被引：91

作者：

Kurz, Philipp ^{[1
]}

Berggren, Gustav ^{[1
]}

Anderlund, Magnus F. ^{[1
]}

Styring, Stenbjorn ^{[1
]}

机构：

[1] Uppsala Univ, Angstrom Lab, Dept Photochem & Mol Sci, S-75120 Uppsala, Sweden

来源：

DALTON TRANSACTIONS | 2007年 / 38卷 / 38期

关键词：

D O I：

10.1039/b710761g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A set of six multinuclear manganese complexes was screened for the ability to catalyse reactions yielding O-2 under coherent experimental conditions; we identify a much larger number of manganese compounds than previously known that catalyse oxygen formation.

引用

页码：4258 / 4261

页数：4

共 37 条

[1] PHOTOCHEMICAL PRODUCTION OF HYDROGEN AND OXYGEN FROM WATER - A REVIEW AND STATE-OF-THE-ART [J].

AMOUYAL, E .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1995, 38 (1-4) :249-276

[2] Redox chemistry of a dimanganese(II,III) complex with an unsymmetric ligand:: Water binding, deprotonation and accumulative light-induced oxidation [J].

Anderlund, Magnus F. ;

Hogblom, Joakim ;

Shi, Wei ;

Huang, Ping ;

Eriksson, Lars ;

Weihe, Hogni ;

Styring, Stenbjorn ;

Akermark, Bjorn ;

Lomoth, Reiner ;

Magnuson, Ann .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (24) :5033-5047

[3] Biologically relevant mono- and di-nuclear manganese II/III/IV complexes of mononegative pentadentate ligands [J].

Baffert, C ;

Collomb, MN ;

Deronzier, A ;

Kjærgaard-Knudsen, S ;

Latour, JM ;

Lund, KH ;

McKenzie, CJ ;

Mortensen, M ;

Nielsen, L ;

Thorup, N .

DALTON TRANSACTIONS, 2003, (09) :1765-1772

[4] ARTIFICIAL PHOTOSYNTHESIS - SOLAR SPLITTING OF WATER TO HYDROGEN AND OXYGEN [J].

BARD, AJ ;

FOX, MA .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) :141-145

[5] Mechanism of water oxidation by the μ-oxo dimer [(bpy)2(H2O)RuIIIORuIII(OH2)(bpy)2]4+ [J].

Binstead, RA ;

Chronister, CW ;

Ni, JF ;

Hartshorn, CM ;

Meyer, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (35) :8464-8473

[6] TETRANUCLEAR MANGANESE OXO COMPLEX WITH A 2.7-A MN=MN SEPARATION AND INTRAMOLECULAR H2O=(MU-O) HYDROGEN-BONDED CONTACTS - [MN4O2(TPHPN)2(H2O)2(CF3SO3)2](CF3SO3)3 - POSSIBLE MODE FOR BINDING OF WATER AT THE ACTIVE-SITE OF THE OXYGEN-EVOLVING COMPLEX IN PHOTOSYSTEM-II [J].

CHAN, MK ;

ARMSTRONG, WH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (12) :4985-4986

[7] Speciation of the catalytic oxygen evolution system:: [MnIII/IV2(μ-O)2(terpy)2(H2O)2](NO3)3+HSO5- [J].

Chen, Hongyu ;

Tagore, Ranitendranath ;

Olack, Gerard ;

Vrettos, John S. ;

Weng, Tsu-Chien ;

Penner-Hahn, James ;

Crabtree, Robert H. ;

Brudvig, Gary W. .

INORGANIC CHEMISTRY, 2007, 46 (01) :34-43

[8] General synthesis of di-μ-oxo dimanganese complexes as functional models for the oxygen evolving complex of photosystem II [J].

Chen, HY ;

Tagore, R ;

Das, S ;

Incarvito, C ;

Faller, JW ;

Crabtree, RH ;

Brudvig, GW .

INORGANIC CHEMISTRY, 2005, 44 (21) :7661-7670

[9] Architecture of the photosynthetic oxygen-evolving center [J].

Ferreira, KN ;

Iverson, TM ;

Maghlaoui, K ;

Barber, J ;

Iwata, S .

SCIENCE, 2004, 303 (5665) :1831-1838

[10] STRUCTURE AND REDOX PROPERTIES OF THE WATER-OXIDATION CATALYST [(BPY)2(OH2)RUORU(OH2)(BPY)2]4+ [J].

GILBERT, JA ;

EGGLESTON, DS ;

MURPHY, WR ;

GESELOWITZ, DA ;

GERSTEN, SW ;

HODGSON, DJ ;

MEYER, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3855-3864

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