Eutectic mixture of choline chloride/urea as a green solvent in synthesis of a coordination polymer:: [Zn(O3PCH2CO2)]•NH4

被引:120
作者
Liao, JH [1 ]
Wu, PC [1 ]
Bai, YH [1 ]
机构
[1] Natl Chung Cheng Univ, Dept Chem & Biochem, Chiayi 621, Taiwan
关键词
eutectic mixture; molten salts; coordination polymer; phosphonate;
D O I
10.1016/j.inoche.2005.01.025
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A eutectic mixture of choline chloride/urea is liquid at ambient temperature and is used as a non-volatile reaction medium for the synthesis and crystallization of a novel coordination polymer, Zn(O3PCH2CO2) center dot NH4, in which structure-directing ammonium ions are generated in situ from the partial decomposition of urea. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:390 / 392
页数:3
相关论文
共 24 条
[1]   Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].
Abbott, AP ;
Boothby, D ;
Capper, G ;
Davies, DL ;
Rasheed, RK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147
[2]   Ionic liquids based upon metal halide/substituted quaternary ammonium salt mixtures [J].
Abbott, AP ;
Capper, G ;
Davies, DL ;
Rasheed, R .
INORGANIC CHEMISTRY, 2004, 43 (11) :3447-3452
[3]   Novel solvent properties of choline chloride/urea mixtures [J].
Abbott, AP ;
Capper, G ;
Davies, DL ;
Rasheed, RK ;
Tambyrajah, V .
CHEMICAL COMMUNICATIONS, 2003, (01) :70-71
[4]   A route to high surface area, porosity and inclusion of large molecules in crystals [J].
Chae, HK ;
Siberio-Pérez, DY ;
Kim, J ;
Go, Y ;
Eddaoudi, M ;
Matzger, AJ ;
O'Keeffe, M ;
Yaghi, OM .
NATURE, 2004, 427 (6974) :523-527
[5]  
CHU Q, 2004, J ELECTROCHEM SOC, V148, pC88
[6]   Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J].
Cooper, ER ;
Andrews, CD ;
Wheatley, PS ;
Webb, PB ;
Wormald, P ;
Morris, RE .
NATURE, 2004, 430 (7003) :1012-1016
[7]   SYNTHESIS, STRUCTURE, AND REACTIVITY OF SOME FUNCTIONALIZED ZINC AND COPPER(II) PHOSPHONATES [J].
DRUMEL, S ;
JANVIER, P ;
BARBOUX, P ;
BUJOLIDOEUFF, M ;
BUJOLI, B .
INORGANIC CHEMISTRY, 1995, 34 (01) :148-156
[8]   Ionic liquid (molten salt) phase organometallic catalysis [J].
Dupont, J ;
de Souza, RF ;
Suarez, PAZ .
CHEMICAL REVIEWS, 2002, 102 (10) :3667-3691
[9]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472
[10]   Strategies for the synthesis of porous metal phosphonate materials [J].
Hix, GB ;
Turner, A ;
Kariuki, BM ;
Tremayne, M ;
MacLean, EJ .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (11) :3220-3227