Raman study of triblock polyether/LiCF3SO3 polymeric electrolytes

被引:12
作者
Silva, RA
Silva, GG
Pimenta, MA
机构
[1] Univ Fed Minas Gerais, Dept Fis, BR-30123970 Belo Horizonte, MG, Brazil
[2] Univ Fed Minas Gerais, Dept Quim, BR-31270901 Belo Horizonte, MG, Brazil
关键词
D O I
10.1002/jrs.707
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
A micro-Raman study of triblock polyether/LiCF3SO3 polymeric electrolytes was carried out over a wide range of salt concentrations at room temperature. The different associated species were evidenced by means of a lineshape analysis of the bands related to the symmetric stretching mode yl of the SO3- termination and to the C-S vibration of the CF3SO3- anion. The Raman results reveal that the appearance of new associated species coincides with the saturation of prior species. Copyright (C) 2001 John Wiley & Sons, Ltd.
引用
收藏
页码:369 / 371
页数:3
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