Comments on "How single and bifurcated hydrogen bonds influence proton-migration rate constants, redox, and electronic properties of phenoxyl radicals

被引：23

作者：

Rhile, IJ ^{[1
]}

Mayer, JM ^{[1
]}

机构：

[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 11期

关键词：

electron transfer; hydrogen bonds; oxidation proton; transfer; radicals;

D O I：

10.1002/anie.200461977

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mechanistic reinterpretation of cyclic voltammetry data on hydrogen-bonded phenols precludes the stepwise electron- then proton-transfer pathway suggested by F. Thomas et al. Thermochemical and kinetic results indicate that the phenoxyl-ammonium product is formed directly in the anodic process (see scheme). (Chemical Equation Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1598 / 1599

页数：2

共 22 条

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