Homogeneous catalysis. Use of a ruthenium(II) complex for catalysing the ene reaction

被引：14

作者：

Ellis, WW ^{[1
]}

Odenkirk, W ^{[1
]}

Bosnich, B ^{[1
]}

机构：

[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 12期

关键词：

D O I：

10.1039/a801215f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex trans-[Ru(salen)(NO)(H2O)](+) catalyses the ene reaction between activated enophiles and olefins to give homoallylic alcohols by a stepwise process.

引用

页码：1311 / 1312

页数：2

共 18 条

[1] LEWIS ACID CATALYSIS OF THE ENE ADDITION OF CHLORAL AND BROMAL TO OLEFINS - PRODUCT STUDIES [J].

BENNER, JP ;

GILL, GB ;

PARROTT, SJ ;

WALLACE, B .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1984, (03) :291-313

[2] KINETICS OF ACID + BASES HYDROLYSES OF CHLOROPENTAAMMINERUTHENIUM(3) ION [J].

BROOMHEAD, JA ;

BASOLO, F ;

PEARSON, RG .

INORGANIC CHEMISTRY, 1964, 3 (06) :826-&

[3] REACTIONS OF BETA-PINENE WITH AROMATIC-ALDEHYDES [J].

MAJEWSKI, M ;

BANTLE, GW .

SYNTHETIC COMMUNICATIONS, 1990, 20 (16) :2549-2558

[4]

MICHAMI K, 1991, TETRAHEDRON LETT, V32, P6571

[5] DIASTEREOCONTROL VIA LEWIS ACID-PROMOTED ENE REACTION WITH GLYOXYLATES AND ITS APPLICATION TO STEREOCONTROLLED SYNTHESIS OF A 22R-HYDROXY-23-CARBOXYLATE STEROID SIDE-CHAIN [J].

MIKAMI, K ;

LOH, TP ;

NAKAI, T .

TETRAHEDRON LETTERS, 1988, 29 (48) :6305-6308

[6]

NAKATANI Y, 1978, SYNTHESIS-STUTTGART, P147

[7] HOMOGENEOUS CATALYSIS - A RUTHENIUM-BASED LEWIS-ACID CATALYST FOR THE DIELS-ALDER REACTION [J].

ODENKIRK, W ;

RHEINGOLD, AL ;

BOSNICH, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (16) :6392-6398

[8]

ODENKIRK W, 1992, TETRAHEDRON LETT, V39, P5729

[9] INTRA-MOLECULAR ENE REACTIONS IN ORGANIC-SYNTHESIS [J].

OPPOLZER, W ;

SNIECKUS, V .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (07) :476-486

[10]

SAKAI K, 1972, TETRAHEDRON LETT, P4375

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