Silole-containing polymers: Chemistry and optoelectronic properties

被引:316
作者
Chen, Junwu [1 ]
Cao, Yong [1 ]
机构
[1] S China Univ Technol, Inst Optoelect Mat & Devices, Minist Educ, Key Lab Specially Funct Mat, Guangzhou 510640, Peoples R China
关键词
bis-silicon-bridged stilbene; dibenzosilole; dithienosilole; electroluminescence; photoluminescence; silacyclopentadiene;
D O I
10.1002/marc.200700326
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this review, the synthesis and optoelectronic properties of various pi-conjugated-, sigma-conjugated-, pendanted-, and hyperbranched or dendritic silole-containing polymers (SCPs) are described. So far, substituted silole, dibenzosilole, dithienosilole, and bis-silicon-bridged stilbene have been incorporated into SCPs. The tunable bandgaps from 4.0-1.55 eV, variable fluorescent colors from UV to blue, green, and red (RGB) light, fluorescent chemo-sensors for 2,4,6-trinitrotoluene (TNT)-type explosives, aggregation-induced emission, efficient electroluminescence emissions for RGB lights, phosphorescent hosts with high triplet energy level, efficient solar cells, stable field-effect transistors with high hole mobility in air, and attenuation of strong laser power, are the important features of SCPs.
引用
收藏
页码:1714 / 1742
页数:29
相关论文
共 137 条
  • [1] Organic electroluminescence of silole-incorporated polysilane
    Adachi, A
    Yasuda, H
    Sanji, T
    Sakurai, H
    Okita, K
    [J]. JOURNAL OF LUMINESCENCE, 2000, 87-9 (87) : 1174 - 1176
  • [2] Electroluminescent polymers
    Akcelrud, L
    [J]. PROGRESS IN POLYMER SCIENCE, 2003, 28 (06) : 875 - 962
  • [3] Soluble and processable regioregular poly(3-hexylthiophene) for thin film field-effect transistor applications with high mobility
    Bao, Z
    Dodabalapur, A
    Lovinger, AJ
    [J]. APPLIED PHYSICS LETTERS, 1996, 69 (26) : 4108 - 4110
  • [4] THERMAL AND CATALYTIC POLYMERIZATION OF DIETHYNYLDIPHENYLSILANE
    BARTON, TJ
    IJADIMAGHSOODI, S
    PANG, Y
    [J]. MACROMOLECULES, 1991, 24 (06) : 1257 - 1260
  • [5] Bernius MT, 2000, ADV MATER, V12, P1737, DOI 10.1002/1521-4095(200012)12:23<1737::AID-ADMA1737>3.0.CO
  • [6] 2-N
  • [7] A controlled, iterative synthesis and the electronic properties of oligo[(p-phenyleneethynylene)-alt-(2,5-slioleneethynylene)]s
    Boydston, AJ
    Yin, YS
    Pagenkopf, BL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (33) : 10350 - 10354
  • [8] Synthesis and electronic properties of donor-acceptor π-conjugated siloles
    Boydston, AJ
    Yin, Y
    Pagenkopf, BL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (12) : 3724 - 3725
  • [9] NEW UNSATURATED HETEROCYCLIC SYSTEMS .1.
    BRAYE, EH
    CAPLIER, I
    HUBEL, W
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (21) : 4406 - &
  • [10] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS
    BURROUGHES, JH
    BRADLEY, DDC
    BROWN, AR
    MARKS, RN
    MACKAY, K
    FRIEND, RH
    BURN, PL
    HOLMES, AB
    [J]. NATURE, 1990, 347 (6293) : 539 - 541