Direct high yield synthesis of [Ir(OH)(CO)(PPh(3))(2)] from Vaska's compound by phase-transfer catalysis

被引：4

作者：

AlJibori, SA

机构：

[1] Department of Chemistry, College of Education, University of Tikrit, Tikrit

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 506卷 / 1-2期

关键词：

iridium; Vaska's compound; phase transfer catalysis;

D O I：

10.1016/0022-328X(95)05658-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of Vaska's compound with 50% aqueous sodium hydroxide using benzyl(triethyl)ammonium chloride as phase-transfer catalyst gave [Ir(OH)(CO)(PPh(3))(2)] in high yield.

引用

页码：119 / 119

页数：1

共 8 条

[1]

ALJIBORI SA, 1994, TRANSIT METAL CHEM, V19, P293

[2] REVERSIBLE ADDITION OF CARBON-DIOXIDE TO RHODIUM AND IRIDIUM COMPLEXES [J].

FLYNN, BR ;

VASKA, L .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (17) :703-704

[3]

REED CA, 1973, J CHEM SOC DALTON, P1370

[4]

RESS WM, 1985, ORGANOMETALLICS, V4, P402

[5] SIMPLE SYNTHETIC ROUTE TO D8 COMPLEXES OF RHODIUM AND IRIDIUM - ELECTRONEGATIVITY SCALE FOR ANIONIC LIGANDS [J].

VASKA, L ;

PEONE, J .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (09) :418-&

[6]

VASKA L, 1974, INORG SYNTH, V15, P64

[7]

VERIEZE K, 1968, INORG SYNTH, V11, P101

[8]

WILKINSON G, 1971, INORG SYNTH, V13, P126

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