Humidity sensitive property of Li-doped mesoporous silica SBA-15

被引:79
作者
Geng, Wangchang
Wang, Rui
Li, Xiaotian [1 ]
Zou, Yongcun
Zhang, Tong
Tu, Jinchun
He, Yuan
Li, Nan
机构
[1] Jilin Univ, Dept Mat Sci & Engn, Changchun 130012, Peoples R China
[2] Jilin Univ, Dept Elect Engn, Changchun 130012, Peoples R China
[3] Jilin Univ, Dept Chem, State Key Lab Inorgan Synthesis & Preparat Chem, Changchun 130012, Peoples R China
基金
美国国家科学基金会;
关键词
mesoporous silica; SBA-15; humidity sensitivity; Li doped; sensors;
D O I
10.1016/j.snb.2007.04.021
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Mesoporous silica SBA-15 was synthesized by a sol-gel method, and different level of LiCl was doped into SBA-15 by heat-treating process at 550 degrees C to form a series of samples. These samples and pure SBA-15 were investigated as humidity sensor materials at room temperature within the relative humidity range of 11-95%. It was found that after the doping of LiCl, the humidity sensitivity has been greatly improved, the impedance changed by more than three orders of magnitude over the whole humidity range. This was related to the hydrophilic property of the Li+, and a possible mechanism was provided to explain the humidity sensitive properties. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:323 / 329
页数:7
相关论文
共 27 条
[1]   Intermediate- and high-risk melanoma. [J].
Agarwala S.S. .
Current Treatment Options in Oncology, 2002, 3 (3) :205-217
[2]   ELECTRICAL CONDUCTIVITY OF SILICA GEL IN PRESENCE OF ADSORBED WATER [J].
ANDERSON, JH ;
PARKS, GA .
JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (10) :3662-&
[3]   Investigations on the ion transport mechanism in conducting polymer films [J].
Casalbore-Miceli, G ;
Yang, MJ ;
Camaioni, N ;
Mari, CM ;
Li, Y ;
Sun, H ;
Ling, M .
SOLID STATE IONICS, 2000, 131 (3-4) :311-321
[4]   Relative humidity sensors using porous SiC membranes and Al electrodes [J].
Connolly, EJ ;
Pham, HTM ;
Groeneweg, J ;
Sarro, PM ;
French, PJ .
SENSORS AND ACTUATORS B-CHEMICAL, 2004, 100 (1-2) :216-220
[5]   THE NON-CONFORMIST ION [J].
ERNSBERGER, FM .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1983, 66 (11) :747-750
[6]   Humidity sensing properties of nafion and sol-gel derived SiO2/Nafion composite thin films [J].
Feng, CD ;
Sun, SL ;
Wang, H ;
Segre, CU ;
Stetter, JR .
SENSORS AND ACTUATORS B-CHEMICAL, 1997, 40 (2-3) :217-222
[7]   High temperature humidity monitoring using doped strontium cerate sensors [J].
Hassen, MA ;
Clarke, AG ;
Swetnam, MA ;
Kumar, RV ;
Fray, DJ .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 69 (1-2) :138-143
[8]   Effect of Li+ doping on ZrO2-TiO2 humidity sensor [J].
Jain, MK ;
Bhatnagar, MC ;
Sharma, GL .
SENSORS AND ACTUATORS B-CHEMICAL, 1999, 55 (2-3) :180-185
[9]   Preparation and properties of a humidity sensor based on LiCl-doped porous silica [J].
Kong, LB ;
Zhang, LY ;
Yao, X .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1997, 16 (10) :824-826
[10]   Characterization and photocatalytic properties of titanium-containing mesoporous SBA-15 [J].
Li, G ;
Zhao, XS .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (10) :3569-3573