Mechanisms and kinetics of living radical polymerization: Absolute comparison of theory and experiment

被引：15

作者：

Fukuda, T ^{[1
]}

Yoshikawa, C ^{[1
]}

Kwak, Y ^{[1
]}

Goto, A ^{[1
]}

Tsujii, Y ^{[1
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan

来源：

ADVANCES IN CONTROLLED/LIVING RADICAL POLYMERIZATION | 2003年 / 854卷

关键词：

D O I：

10.1021/bk-2003-0854.ch003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Theories that have been proposed to describe the polymerization rates and polydispersities in living radical polymerization (LRP) were experimentally tested for main branches of LRP including nitroxide-mediated polymerization (NMP), atom transfer radical polymerization (ATRP), iodide-mediated polymerization, and reversible addition-fragmentation chain transfer (RAFT) polymerization. The theories were verified on an absolute scale in both the absence and presence of conventional initiation. The cause for the marked retardation in polymerization rate observed in a dithiobenzoate-mediated RAFT polymerization of styrene was eluciated.

引用

页码：24 / 39

页数：16

共 36 条

[1] Modeling the reversible addition-fragmentation chain transfer process in cumyl dithiobenzoate-mediated styrene homopolymerizations: Assessing rate coefficients for the addition-fragmentation equilibrium [J].