Investigation of the effects of doping and post-deposition treatments on the conductivity, morphology, and work function of poly (3,4-ethylenedioxythiophene)/poly (styrene sulfonate) films

被引:472
作者
Huang, JS [1 ]
Miller, PF
Wilson, JS
de Mello, AJ
de Mello, JC
Bradley, DDC
机构
[1] Univ London Imperial Coll Sci Technol & Med, Blackett Lab, Expt Solid State Phys Grp, London SW7 2BZ, England
[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, Elect Mat Grp, London SW7 2BZ, England
关键词
D O I
10.1002/adfm.200400073
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We investigate the influence of annealing conditions on the physical properties of thin films of poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate) (PEDOT/PSS). In particular, we describe how annealing temperature, the ambient gas, and choice of dopant affect the conductivity, morphology, and work functions of the films. Two specific dopants are considered, sorbitol and glycerol, and broad guidelines are developed for using PEDOT/PSS as a hole-injection electrode in polymeric light-emitting devices, solar cells, and photodetectors.
引用
收藏
页码:290 / 296
页数:7
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共 28 条
  • [1] Structure of thin films of poly(3,4-ethylenedioxythiophene)
    Aasmundtveit, KE
    Samuelsen, EJ
    Pettersson, LAA
    Inganäs, O
    Johansson, T
    Feidenhans, R
    [J]. SYNTHETIC METALS, 1999, 101 (1-3) : 561 - 564
  • [2] [Anonymous], SYNTH MET
  • [3] Internal field screening in polymer light-emitting diodes
    Brewer, PJ
    Lane, PA
    deMello, AJ
    Bradley, DDC
    deMello, JC
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (06) : 562 - 570
  • [4] Quantifying the efficiency of electrodes for positive carrier injection into poly(9,9-dioctylfluorene) and representative copolymers
    Campbell, AJ
    Bradley, DDC
    Antoniadis, H
    [J]. JOURNAL OF APPLIED PHYSICS, 2001, 89 (06) : 3343 - 3351
  • [5] Polymer light-emitting diodes with polyethylene dioxythiophene-polystyrene sulfonate as the transparent anode
    Cao, Y
    Yu, G
    Zhang, C
    Menon, R
    Heeger, AJ
    [J]. SYNTHETIC METALS, 1997, 87 (02) : 171 - 174
  • [6] Stability of the interface between indium-tin-oxide and poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) in polymer light-emitting diodes
    de Jong, MP
    van IJzendoorn, LJ
    de Voigt, MJA
    [J]. APPLIED PHYSICS LETTERS, 2000, 77 (14) : 2255 - 2257
  • [7] Fine tuning work function of indium tin oxide by surface molecular design: Enhanced hole injection in organic electroluminescent devices
    Ganzorig, C
    Kwak, KJ
    Yagi, K
    Fujihira, M
    [J]. APPLIED PHYSICS LETTERS, 2001, 79 (02) : 272 - 274
  • [8] Nano-structured conducting polymer network based on PEDOT-PSS
    Ghosh, S
    Inganäs, O
    [J]. SYNTHETIC METALS, 2001, 121 (1-3) : 1321 - 1322
  • [9] Determination of the emission zone in a single-layer polymer light-emitting diode through optical measurements
    Granlund, T
    Pettersson, LAA
    Inganäs, O
    [J]. JOURNAL OF APPLIED PHYSICS, 2001, 89 (11) : 5897 - 5902
  • [10] Characterization of the PEDOT-PSS system by means of X-ray and ultraviolet photoelectron spectroscopy
    Greczynski, G
    Kugler, T
    Salaneck, WR
    [J]. THIN SOLID FILMS, 1999, 354 (1-2) : 129 - 135