Two-component dendritic gels: Easily tunable materials

被引:200
作者
Hirst, AR
Smith, DK [1 ]
Feiters, MC
Geurts, HPM
Wright, AC
机构
[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
[2] Catholic Univ Nijmegen, Dept Organ Chem, NSRIM, NL-6525 ED Nijmegen, Netherlands
[3] Catholic Univ Nijmegen, Dept Gen Instrumentat, NL-6525 ED Nijmegen, Netherlands
[4] NEWI, Adv Mat, Wrexham LL11 2AW, Wales
关键词
D O I
10.1021/ja036111q
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This paper reports the tunability of a two-component gel system based on dendritic l-lysine with a focal point carboxylic acid group and aliphatic diamines. The microscopic structure and macroscopic properties of the gel can be modulated by changing the concentration of the components, altering their molecular structures, or tuning their relative molar ratio. In the latter case, there is a complete change in the morphology of the gel that has a direct impact on its macroscopic properties, specifically its gel-sol transition temperature. Copyright © 2003 American Chemical Society.
引用
收藏
页码:9010 / 9011
页数:2
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