Transition metal complexes in organic synthesis.: Part 68:: Iron-mediated total synthesis of mukonine and mukonidine by oxidative cyclization with air as the oxidizing agent

被引：64

作者：

Knölker, HJ ^{[1
]}

Wolpert, M ^{[1
]}

机构：

[1] Tech Univ Dresden, Inst Organ Chem, D-01069 Dresden, Germany

来源：

TETRAHEDRON | 2003年 / 59卷 / 28期

关键词：

iron complexes; arylamines; electrophilic substitution; oxidative cyclization; carbazole alkaloids;

D O I：

10.1016/S0040-4020(03)00786-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidative cyclization of 5-(2-amino-5-methoxycarbonylphenyl)-substituted tricarbonyl[eta(4)-cyclohexa-1,3-diene]iron complexes by air in protic medium provides the corresponding tricarbonyl[eta(4)-4a,9a-dihydro-9H-carbazole]iron complexes. This procedure is applied to the total synthesis of the 3-methoxycarbonylcarbazole alkaloids mukonine and mukonidine. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：5317 / 5322

页数：6

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