High-performance self-assembled graphene hydrogels prepared by chemical reduction of graphene oxide

被引:298
作者
Sheng Kai-xuan [1 ]
Xu Yu-xi [1 ]
Li Chun [1 ]
Shi Gao-quan [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
Self-assembly; Graphene; Chemical reduction; Hydrogels; Supercapacitor; GRAPHITE OXIDE; LARGE-AREA; FILMS; SHEETS; CONDUCTIVITY; GELS;
D O I
10.1016/S1872-5805(11)60062-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Three-dimensional self-assembled graphene hydrogels (SGHs) have been fabricated by chemical reduction of graphene oxide (GO) with sodium ascorbate. The SGHs were characterized by scanning electron microscopy, rheological tests, electrical conductivity measurements, X-ray photoelectron spectroscopy. X-ray diffraction, and Raman spectroscopy. Results indicate that the reduction of GO promotes the assembly of graphene sheets. The SGHs are electrically conductive (1 S.m(-1)) and mechanically strong and exhibit excellent electrochemical performance. In 1 mol . L-1 aqueous solution of. H2SO4, the specific capacitance of SGHs was measured to be about 240 F.g(-1) at a discharge current density of 1.2 A.g(-1).
引用
收藏
页码:9 / 15
页数:7
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