Production of polypyrrole fibres by wet spinning

被引:41
作者
Foroughi, Javad [1 ]
Spinks, Geoffrey M. [1 ]
Wallace, Gordon G. [1 ]
Whitten, Philip G. [1 ]
机构
[1] Univ Wollongong, Intelligent Polymer Res Inst, ARC Ctr Excellence Electromat Sci, Wollongong, NSW 2522, Australia
基金
澳大利亚研究理事会;
关键词
polypyrrole; fibre; wet spinning; conducting polymer; electronic textile;
D O I
10.1016/j.synthmet.2007.12.008
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Soluble, doped polypyrrole containing no substituent on the pyrrole ring has been synthesized by the incorporation of the di-(2-ethylhexyl) sulfosuccinate dopant anion, which renders the polymer soluble in various organic solvents. The solutions were amenable to a wet-spinning process that produced continuous doped polypyrrole fibres. The ultimate tensile strength, elastic modulus and elongation at break of the obtained fibres were 25 MPa, 1.5 GPa and 2%, respectively, with an electronic conductivity of similar to 3 S/cm. Cyclic voltarnmetry demonstrated the electroactivity of the polypyrrole fibres. These fibres are likely to be important for electronic textile applications. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:104 / 107
页数:4
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