Stereoselective synthesis of six- and seven-membered ether rings based on the ring expansion

被引：58

作者：

Nakata, T

Nomura, S

Matsukura, H

机构：

[1] Inst. of Phys. and Chemical Research, Wako-shi

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 02期

基金：

日本科学技术振兴机构;

关键词：

D O I：

10.1016/0040-4039(95)02131-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Six- and seven-membered ether rings were stereoselectively synthesized based on the rearrangement of the cyclic ether with the simultaneous ring expansion. Treatment of ether having a mesylate or bromide group as the leaving group on the side chain with Zn(OAc)(2) or AgOAc stereoselectively produced the ring expanded ether in good yield.

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页码：213 / 216

页数：4

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