Tetranuclear iron(III) carboxylate clusters with 1,10-phenanthroline and 2,2′-bipyridine:: a new [Fe4(μ4-OHO)(μ-OH)2]7+ core

被引：22

作者：

Boudalis, AK

Lalioti, N

Spyroulias, GA

Raptopoulou, CP

Terzis, A

Tangoulis, V

Perlepes, SP

机构：

[1] Univ Florence, Dept Chem, I-50144 Florence, Italy

[2] Univ Patras, Dept Chem, GR-26500 Patras, Greece

[3] Univ Patras, Dept Pharm, GR-26500 Patras, Greece

[4] NCSR Demokritos, Inst Mat Sci, GR-15310 Athens, Greece

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 07期

关键词：

D O I：

10.1039/b100854o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions between Fe(ClO4)(3). 6H(2)O, NaO2CMe . 3H(2)O and L-L (L-L=2,2'-bipyridine, 1,10-phenanthroline) in MeCN give complexes [Fe-4(OHO)(OH)(2)(O2CMe)(4)(L-L)(4)](ClO4)(3) whose cations contain the novel [Fe-4(mu (4)-OHO)(mu -OH)(2)](7+) core; magnetic studies indicate that both complexes have S=0 ground states, consistent with the presence of strong antiferromagnetic exchange interactions.

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页码：955 / 957

页数：3

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