Synthesis, characterization and catalytic activity of a Wilkinson's type metal-organic-polyoxometalate hybrid compound

被引：77

作者：

Bar-Nahum, I ^{[1
]}

Neumann, R ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 21期

关键词：

D O I：

10.1039/b310236j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metal-organic-polyoxometalate hybrid compound with two functional centers consisting of a rhodium(I)bis(diphenylphospine) unit connected through two alkylene bridging groups to a lacunary Keggin type polyoxometalate was synthesized and used as an effective, recyclable hydrogenation catalyst in monophasic and aqueous biphasic reaction modes.

引用

页码：2690 / 2691

页数：2

共 28 条

[1]

AMMARI N, 1991, NEW J CHEM, V15, P607

[2]

[Anonymous], 1998, CHEM REV, V98

[3] Organometallic-polyoxometalate hybrid compounds: Metallosalen compounds modified by Keggin type polyoxometalates [J].

Bar-Nahum, I ;

Cohen, H ;

Neumann, R .

INORGANIC CHEMISTRY, 2003, 42 (11) :3677-3684

[4] Development and comparative study of different nanofiltration membranes for recovery of highly charged large ions [J].

Chowdhury, SR ;

ten Elshof, JE ;

Benes, NE ;

Keizer, K .

DESALINATION, 2002, 144 (1-3) :41-46

[5] Main-group element, organic, and organometallic derivatives of polyoxometalates [J].

Gouzerh, P ;

Proust, A .

CHEMICAL REVIEWS, 1998, 98 (01) :77-111

[6] HOMOGENEOUS CATALYSIS BY TRANSITION-METAL OXYGEN ANION CLUSTERS [J].

HILL, CL ;

PROSSERMCCARTHA, CM .

COORDINATION CHEMISTRY REVIEWS, 1995, 143 :407-455

[7]

HU C, 2001, CHEM J INTERNET, P3

[8] SYNTHESIS AND MULTISPECTROSCOPIC CHARACTERIZATION OF ORGANICALLY MODIFIED POLYOXOMETALATES [J].

JUDEINSTEIN, P ;

DEPRUN, C ;

NADJO, L .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (08) :1991-1997

[9] SYNTHESIS AND PROPERTIES OF POLYOXOMETALATES BASED INORGANIC ORGANIC POLYMERS [J].

JUDEINSTEIN, P .

CHEMISTRY OF MATERIALS, 1992, 4 (01) :4-7

[10] DERIVATIVES OF HETEROPOLYANIONS .2. METAL-METAL-BONDED DERIVATIVES [J].

KNOTH, WH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (08) :2211-2213

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