Regioselective additions to Π-allyl metal complexes

被引：17

作者：

Krafft, ME ^{[1
]}

Fu, Z ^{[1
]}

Procter, MJ ^{[1
]}

Wilson, AM ^{[1
]}

Dasse, OA ^{[1
]}

Hirosawa, C ^{[1
]}

机构：

[1] Florida State Univ, Dept Chem, Tallahassee, FL 32306 USA

来源：

PURE AND APPLIED CHEMISTRY | 1998年 / 70卷 / 05期

关键词：

D O I：

10.1351/pac199870051083

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly regioselective additions to allylic acetates, catalyzed by palladium (0), can be achieved by incorporation of a thioether or tertiary amine on the substrate. Reactions with malonate anion are highly selective for the terminus of the allyl moiety proximal to the heteroatom.

引用

页码：1083 / 1090

页数：8

共 22 条

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