The mechanism of formic acid electro oxidation on iron tetrasulfophthalocyanine-modified platinum electrode

被引：25

作者：

Zhang, Zhonghua ^{[1
]}

Zhou, Xiaochun ^{[1
]}

Liu, Changpeng ^{[1
]}

Xing, Wei ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Electroanalyt Chem, Grad Sch Chinese Acad Sci, Changchun 130022, Jilin, Peoples R China

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2008年 / 10卷 / 01期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/j.elecom.2007.10.031

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The mechanism of formic acid electrooxidation on iron tetrasulfophthalocyanine (FeTSPc) modified Pt electrode was investigated with electrochemical methods. It was found that a "third-body" effect of FeTSPc on Pt electrode predominates during the electrooxidation process based on unusual electrochemical results. The modification leads formic acid electrooxidation to take place through a desired direct pathway, in which the mechanism is proposed to be the gradual dehydrogenation of formic acid and the reaction of formate with hydroxyl species. (C) 2007 Elsevier B.V. All rights reserved.

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收藏

页码：131 / 135

页数：5

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