Synthesis and characterization of exfoliated MEH-PPV/clay nanocomposites by in situ polymerization

被引：14

作者：

Jing, CJ

Chen, LS

Shi, Y

Jin, XG ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China

来源：

EUROPEAN POLYMER JOURNAL | 2005年 / 41卷 / 10期

基金：

中国国家自然科学基金;

关键词：

poly(phenylene vinylene); montmorillonite; nanocomposites; luminescence;

D O I：

10.1016/j.eurpolymj.2005.05.007

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this article, we demonstrate the synthesis of a conjugated polymer, poly(2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylene vinylene) (MEH-PPV) in the presence of organophilic montmorillonite (OMMT) and the properties of the MEH-PPV/OMMT composites produced herefrom. By controlling the reaction conditions, such as the ratio of monomeric precursors to montmorillonite, exfoliated MEH-PPV/OMMT nanocomposites were synthesized via in situ polymerization. These materials exhibit higher electroluminescent properties and enhanced performance of thermal stability than that of the pure polymer. Additionally, based on the solid-state C-13 NMR measurement results, the possible origin of the optoelectronic property improvement is discussed from the point of view of segmental mobility. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：2388 / 2394

页数：7

共 30 条

[1] PHOTOVOLTAIC AND PHOTOCONDUCTIVE PROPERTIES OF ALUMINUM POLY(P-PHENYLENE VINYLENE) INTERFACES [J].