New A-A-D-A-A-Type Electron Donors for Small Molecule Organic Solar Cells

被引：66

作者：

Lin, Li-Yen

Lu, Chih-Wei

Huang, Wei-Ching

Chen, Yi-Hong

Lin, Hao-Wu ^{[1
]}

Wong, Ken-Tsung

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 18期

关键词：

EFFICIENCY; OLIGOTHIOPHENES; PHOTOVOLTAICS; OLIGOMERS;

D O I：

10.1021/ol2021077

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two A-A-D-A-A-type molecules (BCNDTS and BDCDTS), where two terminal electron-withdrawing cyano or dicyanovinylene moieties are connected to a central dithienosilole core through another electron-accepting 2,1,3-benzothiadiazole block, have been synthesized, characterized, and employed as electron donors for small molecule organic solar cells. Vacuum-deposited bilayer and planar mixed heterojunction devices based on BCNDTS and fullerene acceptors (C-60 or C-70) exhibited decent power conversion efficiencies of 2.3% and 3.7%, respectively.

引用

收藏

页码：4962 / 4965

页数：4

相关论文

共 36 条

[1] Silicon Atom Substitution Enhances Interchain Packing in a Thiophene-Based Polymer System [J].

Chen, Hsiang-Yu ;

Hou, Jianhui ;

Hayden, Amy E. ;

Yang, Hoichang ;

Houk, K. N. ;

Yang, Yang .

ADVANCED MATERIALS, 2010, 22 (03) :371-+

[2] Synthesis of Conjugated Polymers for Organic Solar Cell Applications [J].

Cheng, Yen-Ju ;

Yang, Sheng-Hsiung ;

Hsu, Chain-Shu .

CHEMICAL REVIEWS, 2009, 109 (11) :5868-5923

[3] Bulk Heterojunction Solar Cells Using Thieno[3,4-c]pyrrole-4,6-dione and Dithieno[3,2-b:2′,3′-d]silole Copolymer with a Power Conversion Efficiency of 7.3% [J].

Chu, Ta-Ya ;

Lu, Jianping ;

Beaupre, Serge ;

Zhang, Yanguang ;

Pouliot, Jean-Remi ;

Wakim, Salem ;

Zhou, Jiayun ;

Leclerc, Mario ;

Li, Zhao ;

Ding, Jianfu ;

Tao, Ye .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (12) :4250-4253

[4] Light-emitting organic solar cells based on a 3D conjugated system with internal charge transfer [J].

Cravino, Antonio ;

Leriche, Philippe ;

Aleveque, Olivier ;

Roquet, Sophie ;

Roncali, Jean .

ADVANCED MATERIALS, 2006, 18 (22) :3033-+

[5] Dicyanovinyl-Substituted Oligothiophenes: Structure-Property Relationships and Application in Vacuum-Processed Small-Molecule Organic Solar Cells [J].

Fitzner, Roland ;

Reinold, Egon ;

Mishra, Amaresh ;

Mena-Osteritz, Elena ;

Ziehlke, Hannah ;

Koerner, Christian ;

Leo, Karl ;

Riede, Moritz ;

Weil, Matthias ;

Tsaryova, Olga ;

Weiss, Andre ;

Uhrich, Christian ;

Pfeiffer, Martin ;

Baeuerle, Peter .

ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (05) :897-910

[6] Synthesis, Characterization, and Photovoltaic Properties of a Low Band Gap Polymer Based on Silole-Containing Polythiophenes and 2,1,3-Benzothiadiazole [J].

Hou, Jianhui ;

Chen, Hsiang-Yu ;

Zhang, Shaoqing ;

Li, Gang ;

Yang, Yang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (48) :16144-+

[7] Fabrication and processing of polymer solar cells: A review of printing and coating techniques [J].

Krebs, Frederik C. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2009, 93 (04) :394-412

[8] Direct Comparison of Highly Efficient Solution- and Vacuum-Processed Organic Solar Cells Based on Merocyanine Dyes [J].

Kronenberg, Nils M. ;

Steinmann, Vera ;

Buerckstuemmer, Hannah ;

Hwang, Jaehyung ;

Hertel, Dirk ;

Wuerthner, Frank ;

Meerholz, Klaus .

ADVANCED MATERIALS, 2010, 22 (37) :4193-+

[9] Triphenylamine/Tetracyanobutadiene-Based D-A-D π-Conjugated Systems as Molecular Donors for Organic Solar Cells [J].

Leliege, Antoine ;

Blanchard, Philippe ;

Rousseau, Theodulf ;

Roncali, Jean .

ORGANIC LETTERS, 2011, 13 (12) :3098-3101

[10] Benzothiadiazole-Based Linear and Star Molecules: Design, Synthesis, and Their Application in Bulk Heterojunction Organic Solar Cells [J].

Li, Weiwei ;

Du, Chun ;

Li, Fenghong ;

Zhou, Yi ;

Fahlman, Mats ;

Bo, Zhishan ;

Zhang, Fengling .

CHEMISTRY OF MATERIALS, 2009, 21 (21) :5327-5334

← 1 2 3 4 →