Stable paramagnetic bis(alkynyl) manganese complexes

被引:22
作者
Krivykh, VV
Eremenko, IL
Veghini, D
Petrunenko, IA
Pountney, DL
Unseld, D
Berke, H
机构
[1] UNIV ZURICH, INST ORGAN CHEM, CH-8057 ZURICH, SWITZERLAND
[2] RUSSIAN ACAD SCI, INST GEN & INORGAN CHEM, MOSCOW 117907, RUSSIA
[3] UNIV ZURICH, INST BIOCHEM, CH-8057 ZURICH, SWITZERLAND
关键词
manganese; alkynyl ligands; X-ray structure; EPR spectroscopy;
D O I
10.1016/0022-328X(95)05926-G
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Stable paramagnetic Mn(II) and Mn(III) bis(alkynyl) complexes of the type [trans(RC=C)(2)Mn(dmpe)(2)](n+) (R=Ph, SiMe(3), n=0.1) have been prepared and characterized by spectroscopic, electrochemical, magnetic measurements and X-ray single crystal diffraction studies.
引用
收藏
页码:111 / 114
页数:4
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