Azido(2,2′-bipyridine)(η5-pentamethylcyclopentadienyl)iridium(III) hexafluorophosphate

被引：9

作者：

Suzuki, T ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805003727

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Ir(C10H15)(N-3)(C10H8N2)]PF6, the linear azide ligand adopts an end-on terminal coordination mode with a relatively long Ir-N bond of 2.230 (6) Angstrom. The azide is asymmetric in an unusual way: the azide N-N bond adjacent to the azide Ir-N bond [1.025 (12) Angstrom] is significantly shorter than the terminal azide N-N bond [1.282 (15) Angstrom], while the azide Ir-N-N bond angle is 116.4 (6)degrees.

引用

页码：M488 / M490

页数：3

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