Effects of isothermal crystallization on fracture toughness and crack growth behavior of poly (lactic acid)

被引:37
作者
Park, SD [1 ]
Todo, M [1 ]
Arakawa, K [1 ]
机构
[1] Kyushu Univ, Appl Mech Res Inst, Fukuoka 8168580, Japan
关键词
D O I
10.1007/s10853-005-6534-z
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A study to characterize the effect of isothermal crystallization on the mode I fracture toughness of polylactic acid (PLA) solids was discussed. An amorphous and six crystallined PLA plates were prepared by quenching and annealing and their crystalline structures were characterized by polarizing optical microscopy (POM). The thermal properties of these six PLA plates were measured by a differential scanning calorimetry (DSC). Mode I fracture toughness was estimated at a quasi-static loading rate and then correlated with the crack growth behavior characterized by POM. A unique dependence of crystallinity on KIC was found and the change of KIC was closely related to the changes of microstructure and crack growth behavior.
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页码:1055 / 1058
页数:4
相关论文
共 18 条
[1]  
*ASTM, 504191A ASTM D
[2]   FATIGUE CRACK LAYER PROPAGATION IN POLYSTYRENE .1. EXPERIMENTAL-OBSERVATIONS [J].
BOTSIS, J ;
CHUDNOVSKY, A ;
MOET, A .
INTERNATIONAL JOURNAL OF FRACTURE, 1987, 33 (04) :263-276
[3]   Preparation and mechanical properties of nanocomposites of poly(D,L-lactide) with Ca-deficient hydroxyapatite nanocrystals [J].
Deng, XM ;
Hao, JY ;
Wang, CS .
BIOMATERIALS, 2001, 22 (21) :2867-2873
[4]  
Fambri L, 2002, INTEGRATED BIOMATERIALS SCIENCE, P119
[5]  
FRIEDRICH K, 1983, ADV POLYM SCI, V52-3, P225
[6]   Biodegradation behavior of ultra-high-strength hydroxyapatite/poly (L-lactide) composite rods for internal fixation of bone fractures [J].
Furukawa, T ;
Matsusue, Y ;
Yasunaga, T ;
Shikinami, Y ;
Okuno, M ;
Nakamura, T .
BIOMATERIALS, 2000, 21 (09) :889-898
[7]   POLYMER HYDROXYAPATITE COMPOSITES FOR BIODEGRADABLE BONE FILLERS [J].
HIGASHI, S ;
YAMAMURO, T ;
NAKAMURA, T ;
IKADA, Y ;
HYON, SH ;
JAMSHIDI, K .
BIOMATERIALS, 1986, 7 (03) :183-187
[8]  
Mohanty AK, 2000, MACROMOL MATER ENG, V276, P1, DOI 10.1002/(SICI)1439-2054(20000301)276:1<1::AID-MAME1>3.0.CO
[9]  
2-W
[10]  
PARK SD, 2003, IN PRESS J MAT SCI L