Gold-promoted styrene polymerization

被引：49

作者：

Urbano, Juan ^{[1
]}

Hormigo, A. Jesus ^{[1
]}

de Fremont, Pierre ^{[2
]}

Nolan, Steven P. ^{[2
]}

Diaz-Requejo, M. Mar ^{[1
]}

Perez, Pedro J. ^{[1
]}

机构：

[1] Univ Huelva, Unidad Asociada CSIC, Dept Quim & Ciencia Mat, Lab Catalisis Homogenea, Huelva 21007, Spain

[2] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 06期

关键词：

D O I：

10.1039/b716145j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Styrene can be polymerized at room temperature in the presence of equimolar mixtures of the gold(III) complexes (NHC)AuBr3 (NHC = N-heterocyclic carbene ligand) and NaBAr4', in the first example of a gold-induced olefin polymerization reaction.

引用

页码：759 / 761

页数：3

共 24 条

[1]

[Anonymous], 2000, NMR SPECTRA POLYM PO

[2] Carbocationic alkene polymerizations initiated by organotransition metal complexes: An alternative, unusual role for soluble Ziegler-Natta catalysts [J].

Baird, MC .

CHEMICAL REVIEWS, 2000, 100 (04) :1471-1478

[3] CATIONIC METAL NITROSYL COMPOUNDS .2. CATALYTIC BEHAVIOR OF CATIONIC COMPLEXES OF IRON [J].

BALLIVET, D ;

BILLARD, C ;

TKATCHENKO, I .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 124 (01) :C9-C11

[4] CATIONIC METAL NITROSYL COMPLEXES .4. POLYMERIZATION OF OLEFINS WITH DINITROSYL IRON COMPLEXES [J].

BALLIVETTKATCHENKO, D ;

BILLARD, C ;

REVILLON, A .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1981, 19 (07) :1697-1706

[5] Highly electrophilic metallocenes and their role in alkene polymerizations [J].

Bochmann, M .

TOPICS IN CATALYSIS, 1999, 7 (1-4) :9-22

[6]

BRAUER G, 1963, HDB PREPARATIVE INOR, P1058

[7] [(3,5-(CF3)2C6H3)4B]-[H(OET2)2]+ - A CONVENIENT REAGENT FOR GENERATION AND STABILIZATION OF CATIONIC, HIGHLY ELECTROPHILIC ORGANOMETALLIC COMPLEXES [J].

BROOKHART, M ;

GRANT, B ;

VOLPE, AF .

ORGANOMETALLICS, 1992, 11 (11) :3920-3922

[8] η6-Arene complexes of Ni(II), efficient catalysts for 1,3-butadiene and styrene polymerization [J].

Cámpora, J ;

Conejo, MD ;

Reyes, ML ;

Mereiter, K ;

Passaglia, E .

CHEMICAL COMMUNICATIONS, 2003, (01) :78-79

[9] Synthesis, characterization and reactivity of N-heterocyclic carbene gold(III) complexes [J].

de Fremont, Pierre ;

Singh, Rohit ;

Stevens, Edwin D. ;

Petersen, Jeffrey L. ;

Nolan, Steven P. .

ORGANOMETALLICS, 2007, 26 (06) :1376-1385

[10] Alkane carbon-hydrogen bond functionalization with (NHC)MCl precatalysts (M = Cu, Au; NHC=N-heterocyclic carbene) [J].

Fructos, MR ;

de Frémont, P ;

Nolan, SP ;

Díaz-Requejo, MM ;

Pérez, PJ .

ORGANOMETALLICS, 2006, 25 (09) :2237-2241

← 1 2 3 →