Electrochemical insertion of lithium into a doped diamond film grown on carbon felt substrates

This paper summarizes the preliminary results obtained from lithium electrochemical intercalation into boron-doped diamond films grown on carbon felt (BDD/CF electrode). BDD films have been grown by Hot Filaments Chemical Vapor Deposition (HFCVD) and have been characterized by Scanning Electron Microscopy (SEM) and Raman Scattering spectroscopy. BDD/CF composite electrodes, which contain a diamond layer, lead to higher conductivity and smaller grain sizes. In turn, they are richer in boundary or sp(2) sites, and present a reversible specific capacity that is much larger than that of the substrate alone, indicating that the diamond layer effectively participates in lithium storage. Diamond layers displaying boron doping levels of 10(19) and 10(21) part cm(-3) provide a specific capacity of 160 and 370 mA h g(-1), respectively, which is associated with lithium storage. (c) 2005 Elsevier B.V. All rights reserved.