A novel azido and pyrazine-dioxide bridged three-dimensional manganese(II) network with antiferromagnetic ordering (TN=62 K) and a spin flop state

被引:82
作者
Ma, BQ
Sun, HL
Gao, S [1 ]
Su, G
机构
[1] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
[2] Peking Univ, PKU HKU Joint Lab Rare Earth Mat & Bioinorgan Che, Beijing 100871, Peoples R China
[3] Univ Sci & Technol China, Grad Sch Beijing, Dept Phys, CAS, Beijing 100039, Peoples R China
关键词
D O I
10.1021/cm000941a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel three-dimensional network, Mn(N3)2(pzdo), bridged by azido and pzdo (pzdo = pyrazine-dioxide) has been synthesized and structurally and magnetically characterized. It possesses a cubic-like structure and shows an antiferromagnetic ordering at higher temperature (62 K) and a spin-flop transition.
引用
收藏
页码:1946 / 1948
页数:3
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