Bidirectional asymmetric allylboration and the synthesis of C2 symmetric 3-methylenepentane-1,5-diols

被引：13

作者：

Barrett, AGM ^{[1
]}

Braddock, DC ^{[1
]}

de Koning, PD ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, London SW7 2AY, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 05期

关键词：

D O I：

10.1039/a808070d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The double allylboration of aldehydes using 1,3-bis(diisopinocampheylboryl)-2-methylenepropane under Brown's salt-free conditions provides Ct symmetric 3-methylenepentane-1,5-diols in excellent enantiomeric excess.

引用

页码：459 / 460

页数：2

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