One-Pot Synthesis of Silica@Coordination Polymer Core-Shell Microspheres with Controlled Shell Thickness

被引：72

作者：

Jo, Chiho ^{[1
]}

Lee, Hee Jung ^{[1
]}

Oh, Moonhyun ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 15期

关键词：

METAL-ORGANIC-FRAMEWORK; SELF-ASSEMBLED MONOLAYERS; COLLOIDAL PARTICLES; GROWTH; MICROPARTICLES; MEMBRANE; TOPOLOGY;

D O I：

10.1002/adma.201004208

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metal-mediated coordination polymerization method is demonstrated to immobilize organic molecules onto silica particles in the form of coordination polymers. Unique silica@coordination polymer core-shell microspheres are generated, in which the shell thickness is controlled from 65 to 295 nm by varying the amount of coordination polymer precursors or silica particles.

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页码：1716 / +

页数：5

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