Perturbed hard-sphere-chain theory modeling of vapor-liquid equilibria of high concentration polymer and copolymer systems

被引：11

作者：

Feng, W

Wen, H ^{[1
]}

Xu, ZH

Wang, WC

机构：

[1] Chinese Acad Sci, Lab Comp Chem, Inst Chem Met, Beijing 100080, Peoples R China

[2] Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China

来源：

FLUID PHASE EQUILIBRIA | 2001年 / 183卷

关键词：

equation of state; vapor-liquid equilibria; polymer solution;

D O I：

10.1016/S0378-3812(01)00424-1

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Perturbed hard-sphere-chain (PHSC) theory equation of state (EOS), which is based on the square-well model of Alder et al. is applied to calculate and predict the solubilities of solvents and gases in polymers and copolymer. The calculations with one temperature-independent binary parameter K-12, and the predictions with K-12 = 0 are performed for 29 polymer solutions and 9 copolymer mixtures. The obtained results show that this EOS can describe vapor-liquid equilibria(VLE) of high concentration polymer and copolymer solutions very well. The purely predicted results show that the equation has very good predicting potential. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：99 / 109

页数：11

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