Optimization of biodiesel production from castor oil

被引:104
作者
Da Silva, Nivea De Lima [1 ]
Wolf Maciel, Maria Regina [1 ]
Batistella, Cesar Benedito [1 ]
Filho, Rubens Maciel [1 ]
机构
[1] Univ Estadual Campinas, Sch Chem Engn, LDPS, BR-13081970 Campinas, SP, Brazil
关键词
biodiesel; castor oil; ethanolysis; transesterification; alkaline catalyst;
D O I
10.1385/ABAB:130:1:405
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The transesterification of castor oil with ethanol in the presence of sodium ethoxide as catalyst is an exceptional option for the Brazilian biodiesel production, because the castor nut is quite available in the country. Chemically, its oil contains about 90% of ricinoleic acid that gives to the oil some beneficial characteristics such as its alcohol solubility at 30 C. The transesterification variables studied in this work were reaction temperature, catalyst concentration and alcohol oil molar ratio. Through a star configuration experimental design with central points, this study shows that it is possible to achieve the same conversion of esters carrying out the transesterification reaction with a smaller alcohol quantity, and a new methodology was developed to obtain high purity biodiesel.
引用
收藏
页码:405 / 414
页数:10
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