Organic reaction in water. Part 2. A new method for dechlorination of chlorobiphenyls using a Raney Ni-Al alloy in dilute aqueous alkaline solution

被引：48

作者：

Liu, GB ^{[1
]}

Tsukinoki, T ^{[1
]}

Kanda, T ^{[1
]}

Mitoma, Y ^{[1
]}

Tashiro, M ^{[1
]}

机构：

[1] Tohwa Univ, Tohwa Inst Sci, Minami Ku, Fukuoka 8158510, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(98)01230-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Use of a Raney Ni-Al alloy in dilute aqueous alkaline solution gave rise to strong reducing power and chlorobiphenyls were reduced easily to biphenyl and/or phenylcyclohexane, respectively, without any organic solvents. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：5991 / 5994

页数：4

共 15 条

[1] MECHANISTIC ASPECTS OF THE TRIETHYLAMINE ASSISTED PHOTOINDUCED DEHALOGENATION OF HALOGENO-AROMATIC COMPOUNDS
DAVIDSON, RS
GOODIN, JW
[J]. TETRAHEDRON LETTERS, 1981, 22 (02) : 163 - 166
[2] ENHANCED PHOTODEHALOGENATION OF CHLOROBIPHENYLS
EPLING, GA
FLORIO, E
[J]. TETRAHEDRON LETTERS, 1986, 27 (06) : 675 - 678
[3] BOROHYDRIDE-ENHANCED PHOTODEHALOGENATION OF AROCLOR-1232, AROCLOR-1242, AROCLOR-1254, AND AROCLOR-1260
EPLING, GA
MCVICAR, WM
KUMAR, A
[J]. CHEMOSPHERE, 1988, 17 (07) : 1355 - 1362
[4] EFFICIENT AND STABLE PHOTOCATALYTIC SYSTEMS FOR REDUCTIVE DECHLORINATION OF PARA-CHLOROBIPHENYL BY SODIUM-BOROHYDRIDE
ISHIKAWA, M
FUKUZUMI, S
[J]. CHEMISTRY LETTERS, 1990, (06) : 963 - 966
[5] 10-METHYLACRIDINE DERIVATIVES ACTING AS EFFICIENT AND STABLE PHOTOCATALYSTS IN REDUCTIVE DEHALOGENATION OF HALOGENATED COMPOUNDS WITH SODIUM-BOROHYDRIDE VIA PHOTOINDUCED ELECTRON-TRANSFER
ISHIKAWA, M
FUKUZUMI, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (24) : 8864 - 8870
[6] TITANIUM CATALYZED REDUCTION OF AROMATIC HALIDES BY SODIUM-BOROHYDRIDE
LIU, YM
SCHWARTZ, J
[J]. TETRAHEDRON, 1995, 51 (15) : 4471 - 4482
[7] PETERSEN D, 1990, Z NATURFORSCH B, V45, P1105
[8] HYDROGENOLYSIS OF POLYCHLORINATED-BIPHENYLS BY SODIUM-BOROHYDRIDE WITH HOMOGENEOUS AND HETEROGENEOUS NICKEL-CATALYSTS
ROTH, JA
DAKOJI, SR
HUGHES, RC
CARMODY, RE
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1994, 28 (01) : 80 - 87
[9] STOJKOVSKI S, 1991, J CHEM TECHNOL BIOT, V51, P407
[10] DECHLORINATION OF 4-CHLOROBIPHENYL MEDIATED BY AROMATIC PHOTOCATALYSTS
TANAKA, Y
URYU, T
OHASHI, M
TSUJIMOTO, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (22) : 1703 - 1704

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