Synthesis of monodisperse spiro-bridged ladder-type oligo-p-phenylenes

被引:63
作者
Wu, Yonggang [1 ]
Zhang, Jianyuan [1 ]
Bo, Zhishan [1 ]
机构
[1] Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
关键词
D O I
10.1021/ol7017533
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Monodisperse spiro-bridged ladder-type oligo-p-phenylenes, which have very rigid backbones, exhibited intensive emissions with very small Stocks shifts, displayed very good color stability upon thermo-oxidation, and were synthesized by Suzuki cross-coupling, oxidation, and BF3-ether-catalyzed cyclization reactions.
引用
收藏
页码:4435 / 4438
页数:4
相关论文
共 21 条
[1]   Planar para-phenylene oligomers [J].
Grimme, J ;
Scherf, U .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (07) :2297-2304
[2]   Polyphenylene-type emissive materials:: Poly(para-phenylene)s, polyfluorenes, and ladder polymers [J].
Grimsdale, Andrew C. ;
Muellen, Klaus .
EMISSIVE MATERIALS: NANOMATERIALS, 2006, 199 :1-82
[3]   Dispirofluorene-indenofluorene (DSFIF): Synthesis, electrochemical, and optical properties of a promising new family of luminescent materials [J].
Horhant, D ;
Liang, JJ ;
Virboul, M ;
Poriel, C ;
Alcaraz, G ;
Rault-Berthelot, J .
ORGANIC LETTERS, 2006, 8 (02) :257-260
[4]   A fully aryl-substituted poly(ladder-type pentaphenylene):: A remarkably stable blue-light-emitting polymer [J].
Jacob, J ;
Sax, S ;
Gaal, M ;
List, EJW ;
Grimsdale, AC ;
Müllen, K .
MACROMOLECULES, 2005, 38 (24) :9933-9938
[5]   Study on the formation of the ketonic defects in the thermal degradation of ladder-type poly(p-phenylenes) by vibrational spectroscopy [J].
Liu, LL ;
Qiu, S ;
Wang, BL ;
Zhang, W ;
Lu, P ;
Xie, ZQ ;
Hanif, M ;
Ma, YG ;
Shen, JC .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (49) :23366-23370
[6]   On-chain defect emission in conjugated polymers - Comment on 'Exciton dissociation dynamics in a conjugated polymer containing aggregate states' - [A. Haugeneder, U. Lemmer, U. Scherf, Chem. Phys. Lett. 351 (2002) 354] [J].
Lupton, JM .
CHEMICAL PHYSICS LETTERS, 2002, 365 (3-4) :366-368
[7]   Blue-emitting carbon- and nitrogen-bridged poly(ladder-type tetraphenylene)s [J].
Mishra, Ashok K. ;
Graf, Michael ;
Grasse, Florian ;
Jacob, Josemon ;
List, Emil J. W. ;
Muellen, Klaus .
CHEMISTRY OF MATERIALS, 2006, 18 (12) :2879-2885
[8]   Spiro compounds for organic electroluminescence and related applications [J].
Pudzich, R. ;
Fuhrmann-Lieker, T. ;
Salbeck, J. .
EMISSIVE MATERIALS: NANOMATERIALS, 2006, 199 :83-142
[9]   New ladder-type poly(p-phenylene)s containing fluorene unit exhibiting high efficient electroluminescence [J].
Qiu, S ;
Lu, P ;
Liu, X ;
Shen, FZ ;
Liu, LL ;
Ma, YG ;
Shen, JC .
MACROMOLECULES, 2003, 36 (26) :9823-9829
[10]   OXIDATION OF CARBANIONS .I. OXIDATION OF TRIARYL CARBANIONS AND OTHER TERTIARY CARBANIONS [J].
RUSSELL, GA ;
BEMIS, AG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (23) :5491-&