Electronic structure of pentacene adsorbates on Au(111) surfaces

被引:17
作者
Suzuki, T
Kurahashi, M
Ju, X
Yamauchi, Y
机构
[1] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan
[2] CREST, JST, Tsukuba, Ibaraki 3050047, Japan
关键词
D O I
10.1063/1.1630161
中图分类号
O59 [应用物理学];
学科分类号
摘要
The electronic structure of pentacene deposited on a Au(111) substrate in the initial stage of growth was investigated using metastable deexcitation spectroscopy. The occupation of the pentacene pi(*) 4b(1u) orbital, which corresponds to the lowest unoccupied molecular orbital of the gas phase species, was found at the Fermi level. The donation and backdonation-type interactions between the pentacene adsorbate and the Au surface are discussed. (C) 2003 American Institute of Physics.
引用
收藏
页码:4342 / 4344
页数:3
相关论文
共 17 条
[1]  
[Anonymous], UNPUB
[2]  
BOSCHI J, 1972, FARADAY DISCUSS, V54, P116
[3]   Scattering and recoiling imaging code (SARIC) [J].
Bykov, V ;
Kim, C ;
Sung, MM ;
Boyd, KJ ;
Todorov, SS ;
Rabalais, JW .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1996, 114 (3-4) :371-378
[4]   APPLICATIONS OF PHOTOELECTRON SPECTROSCOPY .37. PI-ORBITAL ENERGIES OF ACENES [J].
CLARK, PA ;
HEILBRON.E ;
BROGLI, F .
HELVETICA CHIMICA ACTA, 1972, 55 (05) :1415-&
[5]   Electron spectroscopy using metastable atoms as probes for solid surfaces [J].
Harada, Y ;
Masuda, S ;
Ozaki, H .
CHEMICAL REVIEWS, 1997, 97 (06) :1897-1952
[6]  
Ishii H, 1999, ADV MATER, V11, P605, DOI 10.1002/(SICI)1521-4095(199906)11:8<605::AID-ADMA605>3.0.CO
[7]  
2-Q
[8]   Pi-stacked pentacene thin films grown on Au(111) [J].
Kang, JH ;
Zhu, XY .
APPLIED PHYSICS LETTERS, 2003, 82 (19) :3248-3250
[9]   Conjugated organic molecules on metal versus polymer electrodes: Demonstration of a key energy level alignment mechanism [J].
Koch, N ;
Kahn, A ;
Ghijsen, J ;
Pireaux, JJ ;
Schwartz, J ;
Johnson, RL ;
Elschner, A .
APPLIED PHYSICS LETTERS, 2003, 82 (01) :70-72
[10]   A metastable-atom deexcitation spectroscopy (MDS) study of water adsorption on Cu(100): a new feature at around the Fermi level [J].
Kurahashi, M ;
Suzuki, T ;
Ju, X ;
Yamauchi, Y .
CHEMICAL PHYSICS LETTERS, 2003, 377 (5-6) :519-522