Extended lithium ion pair indicator scale in tetrahydrofuran

被引:37
作者
Streitwieser, A [1 ]
Wang, DZ [1 ]
Stratakis, M [1 ]
Facchetti, A [1 ]
Gareyev, R [1 ]
Abbotto, A [1 ]
Krom, JA [1 ]
Kilway, KV [1 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
关键词
ion pair acidity; organolithium compounds; indicator; acidity scale;
D O I
10.1139/cjc-76-6-765
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The lithium pK scale has been extended to 25 indicators with a pK range of 9.7-24.4. The resulting scale is compared with the cesium ion pair acidities and to ionic pK's in DMSO and aqueous DMSO.
引用
收藏
页码:765 / 769
页数:5
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