Diels-Alder reactions of tetraphenylcyclopentadienones in nanochannels:: Fabrication of nanotubes from hyperbranched polyphenylenes

被引:65
作者
Zhi, LJ
Wu, JS
Li, JX
Stepputat, M
Kolb, U
Müllen, K
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
[2] Johannes Gutenberg Univ Mainz, Inst Phys Chem, D-55128 Mainz, Germany
关键词
D O I
10.1002/adma.200500290
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hyperbranched polyphenylene nanotubes are fabricated by Diels-Alder reactions of tetraphenylcyclopentadienones in the nanochannels of porous alumina membranes. Nanotubes with different structures and morphologies, and even highly porous carbon nanotubes (see Figure), can be obtained by adjusting the starting materials and the conditions of in-situ polymerization.
引用
收藏
页码:1492 / 1496
页数:5
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