Kinetics of aqueous phase reactions relevant for atmospheric chemistry

被引：280

作者：

Herrmann, H ^{[1
]}

机构：

[1] Leibniz Inst Tropospharenforsch, D-04318 Leipzig, Germany

来源：

CHEMICAL REVIEWS | 2003年 / 103卷 / 12期

关键词：

D O I：

10.1021/cr020658q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The determination of kinetic parameters in liquid phase reactions, relevant to atmospheric chemistry, was analyzed. The results were used for chemical mechanism construction for tropospheric cloud and aerosol chemistry models. In the tropospheric system, solution reactions might occur in the droplets of fog, clouds, and rain at low ionic strengths. A simple model was suggested to account for primary kinetic salt effects in reactions involving an ion and a neutral species. The ion-pairing model was able to explain aqueous phase atmospheric chemical conversion.

引用

页码：4691 / 4716

页数：26

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