The reduction of CO2 on polyaniline electrode in a membrane cell

被引:36
作者
Köleli, F [1 ]
Röpke, T
Hamann, CH
机构
[1] Mersin Univ, Fac Arts & Sci, Dept Chem, TR-33342 Mersin, Turkey
[2] Univ Oldenburg, D-26111 Oldenburg, Germany
关键词
polyaniline; CO2; reduction; membrane cell;
D O I
10.1016/S0379-6779(03)00021-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electrochemical reduction of CO2 has been investigated on polyaniline (PAn) electrode at -0.4 V-SCE in a Nafion((R)) 417 membrane cell at ambient conditions by using methanol as a solvent. As reaction product has been found formic acid and acetic acid. The maximum Faradaic efficiencies of the products were found to be 12% for formic acid and 78% for acetic acid. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:65 / 68
页数:4
相关论文
共 24 条
[1]   Electrochemical reduction of CO2 on a polyaniline electrode under ambient conditions and at high pressure in methanol [J].
Aydin, R ;
Köleli, F .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2002, 535 (1-2) :107-112
[2]   ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE ON VARIOUS METAL-ELECTRODES IN LOW-TEMPERATURE AQUEOUS KHCO3 MEDIA [J].
AZUMA, M ;
HASHIMOTO, K ;
HIRAMOTO, M ;
WATANABE, M ;
SAKATA, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (06) :1772-1778
[3]   CARBON-DIOXIDE REDUCTION AT LOW-TEMPERATURE ON VARIOUS METAL-ELECTRODES [J].
AZUMA, M ;
HASHIMOTO, K ;
HIRAMOTO, M ;
WATANABE, M ;
SAKATA, T .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 260 (02) :441-445
[4]   MECHANISM OF REDUCTION OF LEAD IONS IN AQUEOUS-SOLUTION - PULSE-RADIOLYSIS STUDY [J].
BREITENKAMP, M ;
HENGLEIN, A ;
LILIE, J .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1976, 80 (10) :973-979
[5]   ELEMENTARY REACTIONS OF THE REDUCTION OF T1+ IN AQUEOUS-SOLUTION [J].
BUTLER, J ;
HENGLEIN, A .
RADIATION PHYSICS AND CHEMISTRY, 1980, 15 (05) :603-612
[6]   EVIDENCE FOR FORMALDEHYDE, FORMIC-ACID, AND ACETALDEHYDE AS POSSIBLE INTERMEDIATES DURING ELECTROCHEMICAL CARBON-DIOXIDE REDUCTION AT COPPER [J].
COOK, RL ;
MACDUFF, RC ;
SAMMELLS, AF .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (07) :1982-1984
[7]   Large current density CO2 reduction under high pressure using gas diffusion electrodes [J].
Hara, K ;
Sakata, T .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997, 70 (03) :571-576
[8]   Electrocatalytic formation of CH4 from CO2 on a Pt gas diffusion electrode [J].
Hara, K ;
Sakata, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (02) :539-545
[9]   PRODUCTION OF CO AND CH4 IN ELECTROCHEMICAL REDUCTION OF CO2 AT METAL-ELECTRODES IN AQUEOUS HYDROGENCARBONATE SOLUTION [J].
HORI, Y ;
KIKUCHI, K ;
SUZUKI, S .
CHEMISTRY LETTERS, 1985, (11) :1695-1698
[10]   SELECTIVE FORMATION OF FORMIC-ACID, OXALIC-ACID, AND CARBON-MONOXIDE BY ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE [J].
IKEDA, S ;
TAKAGI, T ;
ITO, K .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (07) :2517-2522