Aluminum-magnesium complexes with linearly bridging carbon dioxide

被引：19

作者：

Chang, CC ^{[1
]}

Liao, MC

Chang, TH

Peng, SM

Lee, GH

机构：

[1] Natl Sun Yat Sen Univ, Dept Chem, Kaohsiung 804, Taiwan

[2] Natl Taiwan Univ, Dept Chem, Taipei 117, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 45期

关键词：

aluminum; carbon dioxide fixation; coordination modes; magnesium;

D O I：

10.1002/anie.200502400

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The linear μ(O,O′) bonding mode of CO2 has been found for the first time in the magnesium-aluminum compounds [{R2Al(μ-NSiMe3) (μ-OSiMe 3)Mg(thf)2(μ-O2Q}3] (1 (R = Me) and 2 (R = Et); THF ligands omitted), which were obtained by bubbling CO 2 through a mixture of AlR3 and Mg[N(SiMe 3)2]2 in THF. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7418 / 7420

页数：3

共 22 条

[1]

Behr A., 1988, Angew. Chem., V100, P681, DOI [10.1002/anie.198806611, DOI 10.1002/ANIE.198806611]

[2]

Brisdon A. K., 1998, INORGANIC SPECTROSCO, P23

[3] Carboxylate-shift-like dynamic equilibrium in bromomagnesium diethylcarbamate [J].

Caudle, MT ;

Kampf, JW .

INORGANIC CHEMISTRY, 1999, 38 (24) :5474-+

[4] Chemistry of the organodiamides of magnesium, aluminum and mixed Mg-Al systems. A review of the heterocumulene reactivity on the Mg-Al centers [J].

Chang, CC ;

Ameerunisha, MS .

COORDINATION CHEMISTRY REVIEWS, 1999, 189 :199-278

[5] FIXATION OF CO2 BY A SERIES OF ETHYNYL-BRIDGED POLYNUCLEAR ALUMINUM-MAGNESIUM COMPLEXES - SYNTHESIS, CHARACTERIZATION, AND CRYSTAL-STRUCTURES OF [ME(2)AL(MU-I-PR2N)(2)MG(MU-C-CR)](2) (R=C6H5, C6H4-P-CH3, T-BU, SIME(3)), [ME(2)AL(MU-ET(2)N)(2)MG(MU-C-CC6H5)](2), ((ME(2)AL)(2)[MU-OOC(I-PR2N)](2)), AND ((ME(2)AL)(2)[(MU-OOC(I-PR2N))(2)]MG-2) [J].

CHANG, CC ;

SRINIVAS, B ;

WU, ML ;

CHIANG, WH ;

CHIANG, MY ;

HSIUNG, CS .

ORGANOMETALLICS, 1995, 14 (11) :5150-5159

[6]

Cornia A, 1999, ANGEW CHEM INT EDIT, V38, P1780, DOI 10.1002/(SICI)1521-3773(19990614)38:12<1780::AID-ANIE1780>3.0.CO

[7]

2-D

[8]

Cornia A., 1999, ANGEW CHEM, V111, P1897

[9] New N,N-diisopropylcarbamato complexes of ruthenium(II) as catalytic precursors for olefin hydrogenation [J].

Dell'Amico, DB ;

Calderazzo, F ;

Englert, U ;

Labella, L ;

Marchetti, F ;

Specos, M .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (19) :3938-3945

[10] Converting carbon dioxide into carbamato derivatives [J].

Dell'Amico, DB ;

Calderazzo, F ;

Labella, L ;

Marchetti, F ;

Pampaloni, G .

CHEMICAL REVIEWS, 2003, 103 (10) :3857-3897

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