A novel class of organogelator based on N-isopropylcholamide and the first observation of fibrous colloidal aggregates

被引:62
作者
Hishikawa, Y
Sada, K
Watanabe, R
Miyata, M [1 ]
Hanabusa, K
机构
[1] Osaka Univ, Grad Sch Engn, Suita, Osaka 5650871, Japan
[2] Shinshu Univ, Fac Text Sci & Technol, Ueda, Nagano 3860018, Japan
关键词
D O I
10.1246/cl.1998.795
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
N-Isopropylcholamide afforded three kinds of matters in organic solvents; organogels, inclusion crystals, and guest-free crystals. The gelation occurred in aromatic liquids in the presence of methanol as a good solvent, while the inclusion crystals were formed when adding ethanol, I-propanol, or acetone as a good solvent. The guest-free crystals were obtained in benzene when using 2-butanone, 2-pentanone, or 3-pentanone. Electron microscopic image of the organogel exhibited that the network was formed by gathering of many colloidal particles of several hundreds nanometers in diameter.
引用
收藏
页码:795 / 796
页数:2
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