Research on Cu2+ transformations of Cu and its oxides particles with different sizes in the simulated uterine solution

被引:42
作者
Cai, SZ [1 ]
Xia, XP [1 ]
Xie, CS [1 ]
机构
[1] Huazhong Univ Sci & Technol, Dept Mat Sci & Engn, State Key Lab Plast Forming Simulat & Mould Techn, Wuhan 430074, Peoples R China
基金
中国国家自然科学基金;
关键词
copper corrosion; XRD; particle; the simulated uterine solution;
D O I
10.1016/j.corsci.2004.06.015
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Cu2+ transformations of Cu and its oxides particles with different sizes in the simulated uterine solution were investigated by absorbance measurements. The corrosion intermediate of Cu nanoparticle in the simulated uterine solution was determined by using XRD technique. The results show that the transformation ratio of Cu nanoparticle is remarkably higher than that of Cu microparticle. Moreover, nanoparticles of CuO and Cu2O can be further transformed into cupric ion with transformation ratio over 90%. The high transformation ratio and the transformation mechanism of nanoparticles are discussed. (c) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1039 / 1047
页数:9
相关论文
共 12 条
[1]   Human spermatozoa motility analysis in a Ringer's solution containing cupric ions [J].
Araya, R ;
Gómez-Mora, H ;
Vera, R ;
Bastidas, JM .
CONTRACEPTION, 2003, 67 (02) :161-163
[2]   Copper corrosion-simulated uterine solutions [J].
Bastidas, JM ;
Cano, E ;
Mora, N .
CONTRACEPTION, 2000, 61 (06) :395-399
[3]   Characterization of copper corrosion products originated in simulated uterine fluids and on packaged intrauterine devices [J].
Bastidas, JM ;
Mora, N ;
Cano, E ;
Polo, JL .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2001, 12 (05) :391-397
[4]  
EKKEHARD W, 1973, CONTRACEPTION, V7, P381
[5]   HEAVY-METALS AND HUMAN-SPERMATOZOA .3. THE TOXICITY OF COPPER IONS FOR SPERMATOZOA [J].
HOLLAND, MK ;
WHITE, IG .
CONTRACEPTION, 1988, 38 (06) :685-695
[6]  
KLESZCZEWSKA E, 1998, TOXICOLOGY LETT S1, V95, P138
[7]   Influence of pH and oxygen on copper corrosion in simulated uterine fluid [J].
Mora, N ;
Cano, E ;
Mora, EM ;
Bastidas, JM .
BIOMATERIALS, 2002, 23 (03) :667-671
[8]   In-situ grazing incidence X-ray diffractometry observation of pitting corrosion of copper in chloride solutions [J].
Sathiyanarayanan, S ;
Sahre, M ;
Kautek, W .
CORROSION SCIENCE, 1999, 41 (10) :1899-1909
[9]   The corrosion behaviour of copper in simulated uterine fluid [J].
Zhang, C ;
Xu, N ;
Yang, B .
CORROSION SCIENCE, 1996, 38 (04) :635-641
[10]  
ZHU JJ, 2002, J CHIN SOC CORROS PR, V20, P81