Ultracold collisions involving heteronuclear alkali metal dimers -: art. no. 200402

被引:70
作者
Cvitas, MT
Soldán, P
Hutson, JM
Honvault, P
Launay, JM
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Univ Rennes, Lab Phys Atomes Lasers Mol & Surfaces, CNRS, UMR 6627, Rennes, France
关键词
D O I
10.1103/PhysRevLett.94.200402
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We carry out the first quantum dynamics calculations on ultracold atom-diatom collisions in isotopic mixtures. The systems studied are spin-polarized Li-7+(LiLi)-Li-6-Li-7, Li-7+Li-6(2), Li-6+(LiLi)-Li-6-Li-7, and Li-6+Li-7(2). Reactive scattering can occur for the first two systems even when the molecules are in their ground rovibrational states, but is slower than vibrational relaxation in homonuclear systems. Implications for sympathetic cooling of heteronuclear molecules are discussed.
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页数:4
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