A new structural type in iron carboxylate cluster chemistry via use of bis-bipyridine ligands:: [Fe6O4Cl4(O2CPh)4L2][FeCl4]2

被引：6

作者：

Grant, CM

Knapp, MJ

Huffman, JC

Hendrickson, DN ^{[1
]}

Christou, G

机构：

[1] Univ Calif San Diego, Dept Chem 0358, La Jolla, CA 92093 USA

[2] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[3] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 16期

关键词：

D O I：

10.1039/a803760d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between FeCl3, NaO2CPh and L [L = 1,2-bis(2,2'-bipyridyl-6-yl)ethane] in MeCN gives the title complex 1 whose cation contains an unusual [Fe-6(mu(3)-O)(4)](10+) core, whereas in MeOH the dinuclear complex [Fe-2(OMe)(2-)Cl-2(O2CPh)L][FeCl4] 2 is obtained; magnetic studies indicate that the cations of 1 and 2 both have S = 0 ground states, consistent with the expected antiferromagnetic exchange interactions.

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页码：1753 / 1754

页数：2

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