First intermolecular Pauson-Khand reaction of 7-azanorbornenes.: Control of the regioselectivity by the effect of the substituents attached to the olefinic partner

被引:10
作者
Arjona, O [1 ]
Csáky, AG [1 ]
Medel, R [1 ]
Plumet, J [1 ]
机构
[1] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Organ 1, E-28040 Madrid, Spain
关键词
D O I
10.1016/S0040-4039(01)00393-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
High regioselectivity in the intermolecular Pauson-Khand reaction of 7-azanorborn-5-enes has been found by using 5-bromo-2-endo-tosyl derivatives as the olefinic partner. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3085 / 3087
页数:3
相关论文
共 21 条
  • [1] The tert-butylsulfinyl group as a highly efficient chiral auxiliary in asymmetric Pauson-Khand reactions
    Adrio, J
    Carretero, JC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (32) : 7411 - 7412
  • [2] 7-AZANORBORNADIENE
    ALTENBACH, HJ
    BLECH, B
    MARCO, JA
    VOGEL, E
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1982, 21 (10): : 778 - 778
  • [3] Control of the regioselectivity in the Pauson-Khand reaction of 7-oxanorbornene derivatives
    Arjona, O
    Csáky, AG
    Murcia, MC
    Plumet, J
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (20) : 7338 - 7341
  • [4] Low-energy pathway for Pauson-Khand reactions:: Synthesis and reactivity of dicobalt hexacarbonyl complexes of chiral ynamines
    Balsells, J
    Vázquez, J
    Moyano, A
    Pericàs, MA
    Riera, A
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (22) : 7291 - 7302
  • [5] Chung YK, 1999, COORDIN CHEM REV, V188, P297
  • [6] DEMEIJERE A, 1990, SYNLETT, P20
  • [7] Derdau V, 2000, EUR J ORG CHEM, V2000, P681, DOI 10.1002/(SICI)1099-0690(200002)2000:4<681::AID-EJOC681>3.0.CO
  • [8] 2-I
  • [9] Geis O, 1998, ANGEW CHEM INT EDIT, V37, P911, DOI 10.1002/(SICI)1521-3773(19980420)37:7<911::AID-ANIE911>3.0.CO
  • [10] 2-O