Microstructure and ionic conductivity of LLTO thin films: Influence of different substrates and excess lithium in the target

被引：39

作者：

Aguesse, Frederic ^{[1
]}

Roddatis, Vladimir ^{[1
]}

Roqueta, Jaume ^{[2
]}

Garcia, Pablo ^{[2
]}

Pergolesi, Daniele ^{[3
]}

Santiso, Jose ^{[2
]}

Kilner, John A. ^{[1
,4
]}

机构：

[1] CIC EnergiGUNE, Parque Tecnol Alava, Minano 01510, Spain

[2] CSIC, ICN2, Inst Catala Nanociencia & Nanotecnol, CERCA, Barcelona, Spain

[3] Paul Scherrer Inst, Villigen PSI, Dept Gen Energy Res, CH-5225 Villigen, Switzerland

[4] Univ London Imperial Coll Sci Technol & Med, Dept Mat, London SW7 2AZ, England

来源：

SOLID STATE IONICS | 2015年 / 272卷

关键词：

Li0.34La0.55TiO3 Li-ion conductor; Thin film electrolytes; Li-ion blocking secondary phase; Pulsed laser deposition; PEROVSKITE; GROWTH;

D O I：

10.1016/j.ssi.2014.12.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The deposition of single phase Li3xLa2/3-xTiO3 (LLTO) thin films remains very challenging. The growth of the perovskite phase is in competition with the insulating La2Ti2O7 phase when prepared at high oxygen pressure by PLD. Nevertheless, we have achieved epitaxial growth of LLTO on different (001) oriented substrates such as LaAlO3, SrTiO3 and MgO despite a large lattice mismatch of up to +8.8%. We also determined the percentage of lithium excess in the target necessary to reach a maximum ionic conductivity. However, the presence of the blocking La2Ti2O7 phase strongly hinders the lithium ion migration and reduces the total conductivity compared to bulk properties. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：1 / 8

页数：8

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