Influence of acid-base property of support on the toluene combustion activity of palladium

被引：23

作者：

Okumura, K ^{[1
]}

Tanaka, H ^{[1
]}

Niwa, M ^{[1
]}

机构：

[1] Tottori Univ, Fac Engn, Dept Mat Sci, Tottori 6808552, Japan

来源：

CATALYSIS LETTERS | 1999年 / 58卷 / 01期

关键词：

toluene combustion; acid-base property of metal oxide; metal-support interaction; X-ray photoelectron spectroscopy;

D O I：

10.1023/A:1019096910470

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Metal-support interaction in the catalytic combustion of toluene was studied, using metal oxides with different acid-base properties as supports. The combustion activity over Pd loaded on strong acidic or basic support was lower than over Pd on weak acidic or basic metal oxides. The study of Pd surface with X-ray photoelectron spectroscopy and reaction order measurement showed that the affinity for oxygen changed according to the acid-base property of support. It was considered that the combustion activity of Pd was controlled by the acid-base property of support through an electronic interaction.

引用

页码：43 / 45

页数：3

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