Modeling of solid-liquid equilibria in naphthalene, normal-alkane and polyethylene solutions

被引：50

作者：

Pan, C

Radosz, M ^{[1
]}

机构：

[1] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA

[2] Louisiana State Univ, Macromol Study Grp, Baton Rouge, LA 70803 USA

来源：

FLUID PHASE EQUILIBRIA | 1999年 / 155卷 / 01期

关键词：

equation of state; SAFT; solid-fluid equilibria; method of calculation; alkanes; polyethylene;

D O I：

10.1016/S0378-3812(98)00454-3

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A solid-liquid equilibrium (SLE) model is developed on the basis of an equation of state referred to as copolymer SAFT. This SLE model is demonstrated for hydrocarbon solutions containing totally and partially crystallizable solutes. Initially regressed and tested on the solubility data for naphthalene, normal-alkane, and polyethylene, this model is used in a sensitivity study to understand the effects of crystallizability, melting temperature, molecular weight, and pressure on solid-liquid and liquid-liquid transitions of polyethylene in subcritical and supercritical propane. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：57 / 73

页数：17

共 26 条

[1] [Anonymous], 1988, ENCY POLYM SCI ENG
[2] Copolymer SAFT equation of state. Thermodynamic perturbation theory extended to heterobonded chains
Banaszak, M
Chen, CK
Radosz, M
[J]. MACROMOLECULES, 1996, 29 (20) : 6481 - 6486
[3] PHASE-DIAGRAMS FOR BINARY POLYMER SYSTEMS EXHIBITING BOTH CRYSTALLIZATION AND LIMITED LIQUID LIQUID MISCIBILITY
BURGHARDT, WR
[J]. MACROMOLECULES, 1989, 22 (05) : 2482 - 2486
[4] SOLUBILITIES OF 2 NORMAL-ALKANES IN VARIOUS SOLVENTS
CHANG, SS
MAUREY, JR
PUMMER, WJ
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1983, 28 (02) : 187 - 189
[5] APPLICATIONS OF AUGMENTED VANDERWAALS THEORY OF FLUIDS .1. PURE FLUIDS
CHEN, SS
KREGLEWSKI, A
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1977, 81 (10): : 1048 - 1052
[6] SOLUBILITY OF AROMATIC HYDROCARBON SOLIDS IN MIXTURES OF BENZENE AND CYCLOHEXANE
CHOI, PB
WILLIAMS, CP
BUEHRING, KG
MCLAUGHLIN, E
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1985, 30 (04) : 403 - 409
[7] Solid-liquid equilibrium of n-alkanes using the chain delta lattice parameter model
Coutinho, JAP
Andersen, SI
Stenby, EH
[J]. FLUID PHASE EQUILIBRIA, 1996, 117 (1-2) : 138 - 145
[8] SOLID LIQUID-PHASE EQUILIBRIA OF BINARY AND TERNARY MIXTURES OF BENZENE AND POLYNUCLEAR AROMATIC-COMPOUNDS
DOMANSKA, U
GROVES, FR
MCLAUGHLIN, E
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1993, 38 (01) : 88 - 94
[9] CORRELATION OF SOLID LIQUID AND VAPOR-LIQUID-EQUILIBRIUM DATA FOR POLYNUCLEAR AROMATIC-COMPOUNDS
GUPTA, A
GUPTA, S
GROVES, FR
MCLAUGHLIN, E
[J]. FLUID PHASE EQUILIBRIA, 1991, 64 : 201 - 211
[10] Solid-liquid-liquid equilibria in polymer solutions
Harismiadis, VI
Tassios, DP
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1996, 35 (12) : 4667 - 4681

← 1 2 3 →