学术探索
学术期刊
新闻热点
数据分析
智能评审

Copper-catalyzed oxidative cleavage of carbon-carbon double bond of enol ethers with molecular oxygen

被引：36
作者：
Tokunaga, M
Shirogane, Y
Aoyama, H
Obora, Y
Tsuji, Y
机构：
[1] Hokkaido Univ, Grad Sch Sci, Catalysis Res Ctr, Kita Ku, Sapporo, Hokkaido 0010021, Japan
[2] Japan Sci & Technol Corp, JST, Kita Ku, Sapporo, Hokkaido 0010021, Japan
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 23期
关键词：
copper catalysts; oxidation; C=C cleavage; molecular oxygen;
D O I：
10.1016/j.jorganchem.2005.05.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel C=C bond cleavage reaction of aromatic enol ethers (1) to give ketones (2) using molecular oxygen as oxidant is described. Among the examined catalysts (Cu(II), Pd(II), Ru(II), and H+), CuCl2 exhibited the highest activity. The reaction proceeded smoothly with several kinds of substrates. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：5378 / 5382
页数：5
相关论文
共 32 条
1234