Caprolactam from Renewable Resources: Catalytic Conversion of 5-Hydroxymethylfurfural into Caprolactone

被引：452

作者：

Buntara, Teddy ^{[3
]}

Noel, Sebastien ^{[3
]}

Phua, Pim Huat ^{[3
]}

Melian-Cabrera, Ignacio ^{[3
]}

de Vries, Johannes G. ^{[1
,2
]}

Heeres, Hero J. ^{[3
]}

机构：

[1] Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands

[2] DSM Innovat Synth BV, NL-6160 MD Geleen, Netherlands

[3] Univ Groningen, Dept Chem Engn, NL-9747 AG Groningen, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 31期

关键词：

biomass; caprolactam; caprolactone; hydroxymethylfurfural; sustainable chemistry; OXYGENATED HYDROCARBONS; BIOMASS; FUELS; PHASE; TRANSFORMATION; DEHYDRATION; CHEMISTRY; HYDROGEN; FRUCTOSE; ALCOHOLS;

D O I：

10.1002/anie.201102156

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Renewable nylon: 5-Hydroxymethylfurfural (HMF), which can be obtained from renewable resources such as D-fructose, was converted into caprolactone with very good overall selectivity in only three steps. The new route involves two hydrogenation steps to obtain 1,6-hexanediol, which was oxidatively cyclized to caprolactone, and then converted into caprolactam. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7083 / 7087

页数：5

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